As of version 1.0, characters who are using Pecok Flower as ascension materials are Jiyan, Rover (Female), Rover (Male) and Encore. You can find this ascension mat from multiple locations in Central Plains, namely Taoyuan Vile and south of Tiderise Cliff.
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All 45 Pecok Flower in Wuthering Waves
You can find the first 30 Pecok Flowers in the marked location above. Take a look at the video guide on top if you didn't see some of the flowers in the open.
For the last 15, you can buy it from Koko in Shifang Pharmacy, Jinzhou. You'll need a total of 45000 Shell Credits to buy all of them.